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Raman Spectograph for Ocean Worlds (RSO): New Capabilities for NASA's Europa Lander, 15-R8834

Principal Investigators
Thomas Moore
Carly Howett
Charity Lander
Inclusive Dates 
02/02/18 - Current

BACKGROUND

Jupiter’s moon Europa has an icy shell covering a large global liquid water ocean with likely hydrothermal vents at the ocean floor – this environment may be conducive to the formation of life. The search for biological signatures on Europa requires a lander mission payload with exquisite capabilities for spectroscopic analysis of ice sample composition to characterize the biological potential. The Deep Ultraviolet (Deep-UV) Raman spectroscopy technique is well suited for key measurements of biologically relevant species, including organics, isotopes, amino acids, and other complex molecules. However, a Raman spectrograph instrument customized for planetary science investigations has not yet flown in space, making this area of study well suited for rapid growth and innovations.

APPROACH

SwRI is developing a high-sensitivity Deep-UV + Visible dual-laser Raman system for spaceflight to address astrobiological science goals applicable to ocean worlds such as Europa. Our Raman Spectrograph for Ocean worlds (RSO) instrument design utilizes a technique called integrating Cavity Enhanced Raman Spectroscopy (iCERS), which was developed by collaborators at Texas A&M University and advanced in a previous internal research program unrelated to space science. This iCERS approach has already demonstrated a few orders of magnitude enhancement of Raman signal and femtomolar level measurement sensitivity, making it well suited to searches for trace biosignatures in icy samples.

  1. Baseline iCERS Deep UV measurements for astrobiology sample types

  2. Beamline tests at MIT to characterize i) fluorescence from MeV electrons and gammas and ii) color center production rate/reflectance degradation vs. dose rate

  3. Analytical modeling of radiation effects, fluorescence yield, etc., for both partially sintered and compressed powder options for the cavity material and design

  4. Detector radiation characterization within landed spacecraft vault

  5. Full measurement background subtraction characterization

  6. Additional solid model, thermal design, and mechanisms tasks

  7. Vibration testing a prototype cavity

ACCOMPLISHMENTS

Several prototype integrating cavities were used to measure ice sample mixtures with amino acids (glycine), deuterated water ice, table salt (NaCl), epsom salt (MgSO4), and methanol ice to demonstrate the capability of the initial bench top device to deliver science measurements (even after irradiation). Radiation tests of custom integrating cavities built at SwRI, fiber optic cables, and candidate laser diodes were conducted in a MeV electron beamline at MIT, with radiation levels representative of the Europa environment. No significant performance degradation was detected, and no background signal noise is expected to result from this source as a result of the intense radiation environment when measuring samples on Europa’s surface. Detailed designs for optical, mechanical, electrical, and laser subsystems were developed as planned prior to submitting proposals in response to NASA’s Instrument Concepts for Europa Exploration 2 and Development and Advancement of Lunar Instrumentation opportunities (Figure 2). Our expectation is that the development of SwRI’s enhanced Raman spectrograph system enables new investigations where exquisite compositional measurements of trace minerals are required, which includes not only the most astrobiologically interesting ocean world environments in the solar system, such as Europa, but the Moon and other planetary bodies as well.

Functional prototype of an iCERS cavity

Figure 1: Functional prototype of an iCERS cavity operating at SwRI.

Concept for the integrating cavity enhanced Raman spectrograph

Figure 2: Concept for our integrating cavity enhanced Raman spectrograph. Subsequent proposals to NASA will move our concept to a TRL 5 brassboard implementation, with TRL 6 quickly achievable in a spaceflight mission program.